Publications

Sherman, S. L.; Nickson, K. N.; Garand, E., Comment on “Microhydration of Biomolecules: Revealing the Native Structures by Cold Ion IR Spectroscopy”. J. Phys. Chem. Lett. 2022, 13 (8), 2046–2050. 10.1021/acs.jpclett.1c02211

Sagan, C. R.; Garand, E., Anion Resonances and Photoelectron Spectroscopy of the Tetracenyl Anion. J. Phys. Chem. A 2021, 125 (32), 7014-7022. 10.1021/acs.jpca.1c05938

Cercola, R.;  Fischer, K. C.;  Sherman, S. L.;  Garand, E.;  Wong, N. G. K.;  Hammerback, L. A.;  Lynam, J. M.;  Fairlamb, I. J. S.; Dessent, C. E. H., Direct Measurement of the Visible to UV Photodissociation Processes for the PhotoCORM TryptoCORM. Chem.-Eur. J 2020, 26 (45), 10297-10306. 10.1002/chem.202001077

Fischer, K. C.; Sherman, S. L.; Garand, E., Competition between Solvation and Intramolecular Hydrogen-Bonding in Microsolvated Protonated Glycine and β-Alanine. The Journal of Physical Chemistry A 2020, 124 (8), 1593-1602. 10.1021/acs.jpca.9b11977

Fischer, K. C.; Sherman, S. L.; Voss, J. M.; Zhou, J.; Garand, E., Microsolvation Structures of Protonated Glycine and L-Alanine. J. Phys. Chem. A 2019, 123 (15), 3355-3366. 10.1021/acs.jpca.9b01578

Thurston, G. K.; Sagan, C. R.; Garand, E., Vibrationally resolved photoelectron spectroscopy of oligothiophene radical anions. J. Chem. Phys. 2019, 151 (16). 10.1063/1.5124925

Voss, J. M.; Fischer, K. C.; Garand, E., Accessing the Vibrational Signatures of Amino Acid Ions Embedded in Water Clusters. Journal of Physical Chemistry Letters 2018, 9 (9), 2246-2250. 10.1021/acs.jpclett.8b00738

Kregel, S. J.; Garand, E., Ground and low lying excited states of phenoxy, 1-naphthoxy, and 2-naphthoxy radicals via anion photoelectron spectroscopy. J. Chem. Phys. 2018, 149 (7). 10.1063/1.5045685

Voss, J. M.; Kregel, S. J.; Fischer, K. C.; Garand, E., IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts. Journal of the American Society for Mass Spectrometry 2018, 29 (1), 42-50. 10.1007/s13361-017-1813-x

Kregel, S. J.; Thurston, G. K.; Garand, E., Photoelectron spectroscopy of anthracene and fluoranthene radical anions. J. Chem. Phys. 2018, 148 (23). 10.1063/1.5036757

Fischer, K. C.; Voss, J. M.; Zhou, J.; Garand, E., Probing Solvation-Induced Structural Changes in Conformationally Flexible Peptides: IR Spectroscopy of Gly3H(+).(H2O). J. Phys. Chem. A 2018, 122 (41), 8213-8221. 10.1021/acs.jpca.8b07546

Voss, J. M.; Fischer, K. C.; Garand, E., Revealing the structure of isolated peptides: IR-IR predissociation spectroscopy of protonated triglycine isomers. J. Mol. Spectrosc. 2018, 347, 28-34. 10.1016/j.jms.2018.03.006

Garand, E., Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps. J. Phys. Chem. A 2018, 122 (32), 6479-6490. 10.1021/acs.jpca.8b05712

Voss, J. M.; Duffy, E. M.; Marsh, B. M.; Garand, E., Mass Spectrometric and Vibrational Characterization of Reaction Intermediates in Ru(bpy)(tpy)(H2O) (2+) Catalyzed Water Oxidation. Chempluschem 2017, 82 (5), 691-694. 10.1002/cplu.201700085

Kregel, S. J.; Thurston, G. K.; Zhou, J.; Garand, E., A multi-plate velocity-map imaging design for high-resolution photoelectron spectroscopy. J. Chem. Phys. 2017, 147 (9). 10.1063/1.4996011

Duffy, E. M.; Voss, J. M.; Garand, E., Vibrational Characterization of Microsolvated Electrocatalytic Water Oxidation Intermediate: [Ru(tpy)(bpy)(OH)]2+(H2O)0-4. Journal of Physical Chemistry A 2017, 121 (29), 5468-5474. 10.1021/acs.jpca.7b05255

Duffy, E. M.; Marsh, B. M.; Voss, J. M.; Garand, E., Characterization of the Oxygen Binding Motif in a Ruthenium Water Oxidation Catalyst by Vibrational Spectroscopy. Angewandte Chemie International Edition 2016, 55 (12), 4079-4082. 10.1002/anie.201600350

Voss, J. M.; Marsh, B. M.; Zhou, J.; Garand, E., Interaction between ionic liquid cation and water: infrared predissociation study of bmim (+)center dot(H2O)(n) clusters. Physical Chemistry Chemical Physics 2016, 18 (28), 18905-18913. 10.1039/c6cp02730j

Marsh, B. M.; Zhou, J.; Garand, E., Charge transfer in MOH(H2O)+ (M = Mn, Fe, Co, Ni, Cu, Zn) complexes revealed by vibrational spectroscopy of mass-selected ions. Physical Chemistry Chemical Physics 2015, 17 (39), 25786-25792. 10.1039/c5cp01522g

Marsh, B. M.; Voss, J. M.; Zhou, J.; Garand, E., Coordination structure and charge transfer in microsolvated transition metal hydroxide clusters MOH (+)( H2O)(1-4). Physical Chemistry Chemical Physics 2015, 17 (35), 23195-23206. 10.1039/c5cp03914b

Marsh, B. M.; Voss, J. M.; Garand, E., A dual cryogenic ion trap spectrometer for the formation and characterization of solvated ionic clusters. J. Chem. Phys. 2015, 143 (20). 10.1063/1.4936360

Duffy, E. M.; Marsh, B. M.; Garand, E., Probing the Hydrogen-Bonded Water Network at the Active Site of a Water Oxidation Catalyst: Ru(bpy)(tpy)(H2O) (2+)center dot(H2O)(0-4). J. Phys. Chem. A 2015, 119 (24), 6326-6332. 10.1021/acs.jpca5b04778

Marsh, B. M.; Zhou, J.; Garand, E., Vibrational spectroscopy of isolated copper(II) complexes with deprotonated triglycine and tetraglycine peptides. RSC Advances 2015, 5 (3), 1790-1795. 10.1039/c4ra09655j

Wolk, A. B.; Leavitt, C. M.; Garand, E.; Johnson, M. A., Cryogenic Ion Chemistry and Spectroscopy. Accounts of Chemical Research 2014, 47 (1), 202-210. 10.1021/ar400125a

Marsh, B. M.; Duffy, E. M.; Soukup, M. T.; Zhou, J.; Garand, E., Intramolecular Hydrogen Bonding Motifs in Deprotonated Glycine Peptides by Cryogenic Ion Infrared Spectroscopy. J. Phys. Chem. A 2014, 118 (22), 3906-3912. 10.1021/jp501936b

Marsh, B. M.; Zhou, J.; Garand, E., Vibrational Spectroscopy of Small Hydrated CuOH+ Clusters. J. Phys. Chem. A 2014, 118 (11), 2063-2071. 10.1021/jp411614t

Prior to UW-Madison

Wolk, A. B.; Garand, E.; Jones, I. M.; Hamilton, A. D.; Johnson, M. A., Quantifying Intrinsic Ion-Driven Conformational Changes in Diphenylacetylene Supramolecular Switches with Cryogenic Ion Vibrational Spectroscopy. J. Phys. Chem. A 2013, 117 (29), 5962-5969. 10.1021/jp3111925

Garand, E.; Fournier, J. A.; Kamrath, M. Z.; Schley, N. D.; Crabtree, R. H.; Johnson, M. A., Characterization of an activated iridium water splitting catalyst using infrared photodissociation of H-2 tagged ions. Physical Chemistry Chemical Physics 2012, 14 (29), 10109-10113. 10.1039/c2cp41490b

Garand, E.; Kamrath, M. Z.; Jordan, P. A.; Wolk, A. B.; Leavitt, C. M.; McCoy, A. B.; Miller, S. J.; Johnson, M. A., Determination of Noncovalent Docking by Infrared Spectroscopy of Cold Gas-Phase Complexes. Science 2012, 335 (6069), 694-698. 10.1126/science.1214948

Stanton, J. F.; Garand, E.; Kim, J.; Yacovitch, T. I.; Hock, C.; Case, A. S.; Miller, E. M.; Lu, Y. J.; Vogelhuber, K. M.; Wren, S. W.; Ichino, T.; Maier, J. P.; McMahon, R. J.; Osborn, D. L.; Neumark, D. M.; Lineberger, W. C., Ground and low-lying excited states of propadienylidene (H2C=C=C:) obtained by negative ion photoelectron spectroscopy. J. Chem. Phys. 2012, 136 (13). 10.1063/1.3696896

Leavitt, C. M.; Wolk, A. B.; Fournier, J. A.; Kamrath, M. Z.; Garand, E.; Van Stipdonk, M. J.; Johnson, M. A., Isomer-Specific IR-IR Double. Resonance Spectroscopy of D-2-Tagged Protonated Dipeptides Prepared in a Cryogenic Ion Trap. Journal of Physical Chemistry Letters 2012, 3 (9), 1099-1105. 10.1021/jz3003074

Yacovitch, T. I.; Garand, E.; Kim, J. B.; Hock, C.; Theis, T.; Neumark, D. M., Vibrationally resolved transition state spectroscopy of the F + H-2 and F + CH4 reactions. Faraday Discussions 2012, 157, 399-414. 10.1039/c2fd20011b

Leavitt, C. M.; Wolk, A. B.; Kamrath, M. Z.; Garand, E.; Van Stipdonk, M. J.; Johnson, M. A., Characterizing the Intramolecular H-bond and Secondary Structure in Methylated GlyGlyH(+) with H-2 Predissociation Spectroscopy. Journal of the American Society for Mass Spectrometry 2011, 22 (11), 1941-1952. 10.1007/s13361-011-0228-3

Klein, K.; Garand, E.; Ichino, T.; Neumark, D. M.; Gauss, J.; Stanton, J. F., Quantitative vibronic coupling calculations: the formyloxyl radical. Theoretical Chemistry Accounts 2011, 129 (3-5), 527-543. 10.1007/s00214-011-0893-0

Yacovitch, T. I.; Kim, J. B.; Garand, E.; van der Poll, D. G.; Neumark, D. M., Slow photoelectron velocity-map imaging spectroscopy of the n-methylvinoxide anion. J. Chem. Phys. 2011, 134 (13). 10.1063/1.3572269

Garand, E.; Neumark, D. M., Study of RgS(-) and RgS (Rg = Ne, Ar, and Kr) via slow photoelectron velocity-map imaging spectroscopy and ab initio calculations. J. Chem. Phys. 2011, 135 (2). 10.1063/1.3605595

Kamrath, M. Z.; Garand, E.; Jordan, P. A.; Leavitt, C. M.; Wolk, A. B.; Van Stipdonk, M. J.; Miller, S. J.; Johnson, M. A., Vibrational Characterization of Simple Peptides Using Cryogenic Infrared Photodissociation of H-2-Tagged, Mass-Selected Ions. Journal of the American Chemical Society 2011, 133 (16), 6440-6448. 10.1021/ja200849g

Yen, T. A.; Garand, E.; Shreve, A. T.; Neumark, D. M., Anion Photoelectron Spectroscopy of C3N- and C5N. J. Phys. Chem. A 2010, 114 (9), 3215-3220. 10.1021/jp9093996

Garand, E.; Wende, T.; Goebbert, D. J.; Bergmann, R.; Meijer, G.; Neumark, D. M.; Asmis, K. R., Infrared Spectroscopy of Hydrated Bicarbonate Anion Clusters: HCO3-(H2O)(1-10). Journal of the American Chemical Society 2010, 132 (2), 849-856. 10.1021/ja9093132

Garand, E.; Yacovitch, T. I.; Zhou, J.; Sheehan, S. M.; Neumark, D. M., Slow photoelectron velocity-map imaging of the CnH- (n=5-9) anions. Chemical Science 2010, 1 (2), 192-201. 10.1039/c0sc00164c

Yacovitch, T. I.; Garand, E.; Neumark, D. M., Slow Photoelectron Velocity-Map Imaging of the i-Methylvinoxide Anion. J. Phys. Chem. A 2010, 114 (42), 11091-11099. 10.1021/jp101930b

Garand, E.; Klein, K.; Stanton, J. F.; Zhou, J.; Yacovitch, T. I.; Neumark, D. M., Vibronic Structure of the Formyloxyl Radical (HCO2) via Slow Photoelectron Velocity-Map Imaging Spectroscopy and Model Hamiltonian Calculations. J. Phys. Chem. A 2010, 114 (3), 1374-1383. 10.1021/jp9067894

Goebbert, D. J.; Garand, E.; Wende, T.; Bergmann, R.; Meijer, G.; Asmis, K. R.; Neumark, D. M., Infrared Spectroscopy of the Microhydrated Nitrate Ions NO3-(H2O)(1-6). J. Phys. Chem. A 2009, 113 (26), 7584-7592. 10.1021/jp9017103

Garand, E.; Yacovitch, T. I.; Neumark, D. M., Slow photoelectron velocity-map imaging spectroscopy of C(3)O(-) and C(3)S(-). J. Chem. Phys. 2009, 131 (5). 10.1063/1.3200927

Garand, E.; Yacovitch, T. I.; Neumark, D. M., Slow photoelectron velocity-map imaging spectroscopy of C2N-, C4N-, and C6N. J. Chem. Phys. 2009, 130 (6). 10.1063/1.3076320

Yacovitch, T. I.; Garand, E.; Neumark, D. M., Slow photoelectron velocity-map imaging spectroscopy of the vinoxide anion. J. Chem. Phys. 2009, 130 (24). 10.1063/1.3157208

Garand, E.; Buchachenko, A. A.; Yacovitch, T. I.; Szczesniak, M. M.; Chalasinski, G.; Neumark, D. M., Study of ArO- and ArO via Slow Photoelectron Velocity-Map Imaging Spectroscopy and Ab Initio Calculations. J. Phys. Chem. A 2009, 113 (16), 4631-4638. 10.1021/jp8113682

Garand, E.; Buchachenko, A. A.; Yacovitch, T. I.; Szczesniak, M. M.; Chalasinski, G.; Neumark, D. M., Study of KrO- and KrO via Slow Photoelectron Velocity-Map Imaging Spectroscopy and ab Initio Calculations. J. Phys. Chem. A 2009, 113 (52), 14439-14446. 10.1021/jp903819m

Sheehan, S. M.; Parsons, B. F.; Zhou, J.; Garand, E.; Yen, T. A.; Moore, D. T.; Neumark, D. M., Characterization of cyclic and linear C(3)H(-) and C(3)H via anion photoelectron spectroscopy. J. Chem. Phys. 2008, 128 (3). 10.1063/1.2812561

Garand, E.; Moula, M. G.; Rowntree, P. A., Localization vs. Conduction: Anionic Excitations in Alkanethiol Self-Assembled Monolayers. Langmuir 2008, 24 (24), 13850-13854. 10.1021/la803036v

Garand, E.; Zhou, J.; Manolopoulos, D. E.; Alexander, M. H.; Neumark, D. M., Nonadiabatic interactions in the Cl+H-2 reaction probed by CIH2- and CID2- photoelectron imaging. Science 2008, 319 (5859), 72-75. 10.1126/science.1150602

Garand, E.; Yacovitch, T. I.; Neumark, D. M., Slow photoelectron imaging spectroscopy of CCO(-) and CCS(-). J. Chem. Phys. 2008, 129 (7). 10.1063/1.2969819

Garand, E.; Goebbert, D.; Santambrogio, G.; Janssens, E.; Lievens, P.; Meijer, G.; Neumark, D. M.; Asmis, K. R., Vibrational spectra of small silicon monoxide cluster cations measured by infrared multiple photon dissociation spectroscopy. Physical Chemistry Chemical Physics 2008, 10 (11), 1502-1506. 10.1039/b716627c

Zhou, J.; Garand, E.; Eisfeld, W.; Neumark, D. M., Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. J. Chem. Phys. 2007, 127 (3). 10.1063/1.2748399

Zhou, J.; Garand, E.; Neumark, D. M., Slow electron velocity-map imaging spectroscopy of the C4H- and C4D- anions. J. Chem. Phys. 2007, 127 (15). 10.1063/1.2795723

Asmis, K. R.; Santambrogio, G.; Zhou, J.; Garand, E.; Headrick, J.; Goebbert, D.; Johnson, M. A.; Neumark, D. M., Vibrational spectroscopy of hydrated electron clusters (H2O)(15-50)(-) via infrared multiple photon dissociation. J. Chem. Phys. 2007, 126 (19). 10.1063/1.2741508

Zhou, J.; Garand, E.; Neumark, D. M., Vibronic structure in C2H and C2D from anion slow electron velocity-map imaging spectroscopy. J. Chem. Phys. 2007, 127 (11). 10.1063/1.2768932

Garand, E.; Rowntree, P. A., The mechanism of hydrogen formation induced by low-energy electron irradiation of hexadecanethiol self-assembled monolayers. Journal of Physical Chemistry B 2005, 109 (26), 12927-12934. 10.1021/jp050817k

Garand, E.; Picard, J. F.; Rowntree, P., Inter- and intramolecular temperature-dependent vibrational perturbations of alkanethiol self-assembled monolayers. Journal of Physical Chemistry B 2004, 108 (24), 8182-8189. 10.1021/jp031273u